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tautomerism
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What is Tautomerism?
Tautomerism is also termed as desmotropism. Examples of Tautomerism. If we consider the simple definition of tautomerism then it is described as a type of isomerism wherein the isomers interchange into or between one another very easily in order to exist together in equilibrium .
tgc.ac.in
tgc.ac.in
Tautomer - Wikipedia
The phenomenon of tautomerization is called tautomerism, also called desmotropism. Tautomerism is for example relevant to the behavior of amino acids and ...
en.wikipedia.org
en.wikipedia.org
Tautomerism Example - BYJU'S
Tautomerism is a phenomenon where a single chemical compound tends to exist in two or more interconvertible structures that are different in terms of the ...
byjus.com
byjus.com
tautomerism
tautomerism Chem. (tɔːˈtɒmərɪz(ə)m) [f. Gr. ταὐτο- tauto- + µέρος part, after isomerism; rendering Ger. tautomerie (Laar 1885).] The property exhibited by certain organic compounds of behaving in different reactions as if they possessed two (or more) different constitutions, that is, as if the atoms...
Oxford English Dictionary
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9.4.2. Tautomers - Chemistry LibreTexts
Tautomers are molecules with the same formula but different connectivity, like constitutional isomers, that interconvert rapidly, such as keto- ...
chem.libretexts.org
chem.libretexts.org
Let's not forget tautomers - PMC
A compound exhibits tautomerism if it can be represented by two structures that are related by an intramolecular movement of hydrogen from one atom to another.
pmc.ncbi.nlm.nih.gov
pmc.ncbi.nlm.nih.gov
1-Naphthol
Reactions and degradation
Some reactions of 1-naphthol are explicable with reference to its tautomerism, which produces a small amount of the keto tautomer One consequence of this tautomerism is the Bucherer reaction, the ammonolysis of 1-naphthol to give 1-aminonaphthalene.
1-Naphthol biodegrades via formation
wikipedia.org
en.wikipedia.org
Tautomerism
Tautomers are isomers of a compound which differ only in the position of the protons and electrons. The carbon skeleton of the compound is unchanged.
vrchemistry.chem.ox.ac.uk
vrchemistry.chem.ox.ac.uk
Keto-Enol Tautomerism : Key Points - Master Organic Chemistry
Many aldehydes and ketones are in equilibrium with a structural isomer known as the enol form (part alkene, part alcohol). This behavior is known as keto-enol ...
www.masterorganicchemistry.com
www.masterorganicchemistry.com
Tautomerism unveils a self-inhibition mechanism of crystallization
We identify tautomers as a new class of modifiers where the dynamic interconversion between solute and its corresponding tautomer(s) produces native crystal ...
www.nature.com
www.nature.com
tautomerism (T06252) - IUPAC Gold Book
where the isomers (called tautomers) are readily interconvertible; the atoms connecting the groups X , Y , Z are typically any of C , H , O or S , and G is ...
goldbook.iupac.org
goldbook.iupac.org
mesomerism
mesomerism Chem. (mɛˈsɒmərɪz(ə)m) [(in sense a) ad. F. mésomérie (A. Cornillot 1927, in Ann. de Chim. VIII. 267), f. meso- meso- after tautomérie tautomerism.] † a. A kind of tautomerism (see quot.). Obs.1928 Chem. Abstr. XXII. 2155 The term mesomerism is proposed to designate affinitive tautomerism...
Oxford English Dictionary
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anionotropy
anioˈnotropy Chem. [f. anion + -o + Gr. -τροπία turning.] Tautomerism characterized by the movement of an anion. So anionoˈtropic a.1928 Burton & Ingold in Jrnl. Chem. Soc. i. 904 It can be seen in a general way that opposite conditions will prevail in mobile-anion tautomerism (anionotropy). Ibid. 9...
Oxford English Dictionary
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Phenylpyruvate tautomerase
catalyzes the chemical reaction
keto-phenylpyruvate enol-phenylpyruvate
Phenylpyruvate tautomerase has also been found to exhibit the same keto-enol tautomerism
wikipedia.org
en.wikipedia.org
2-Naphthol
Reactions
Some reactions of 2-naphthol are explicable with reference to its tautomerism, which produces a small amount of the keto tautomer. One consequence of this tautomerism is the Bucherer reaction, the ammonolysis of 2-naphthol to give 2-aminonaphthalene.
2-Naphthol can be oxidatively
wikipedia.org
en.wikipedia.org