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stereospecific
stereospecific, a. Chem. (ˌstɛriːəʊ-, ˌstɪəriːəʊspɪˈsɪfɪk) Also stereo-specific. [f. stereo- + specific a.] 1. a. Of a reaction: = stereoselective a. Also of a catalyst: causing a reaction to be (more) stereoselective.1949 Jrnl. Amer. Chem. Soc. LXXI. 3866/2 The reaction giving rise to the acetates ...
Oxford English Dictionary
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D-stereospecific aminopeptidase
In molecular biology, D-stereospecific aminopeptidase (D-aminopeptidase) is an enzyme which catalyses the release of an N-terminal D-amino acid from a
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Stereospecificity
In the latter sense, the term stereospecific reaction is commonly misused to mean highly stereoselective reaction. The addition of singlet carbenes to alkenes is stereospecific in that the geometry of the alkene is preserved in the product.
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stereoselective
stereoselective, a. Chem. (ˌstɛriːəʊ-, ˌstɪəriːəʊsɪˈlɛktɪv) [f. stereo- + selective a.] Of a reaction: producing a particular stereoisomeric form of the product preferentially, irrespective of the configuration of the reactant; = stereospecific a. 1 a. Orig. (quot. 1957) = stereospecific a. 2.1957 J...
Oxford English Dictionary
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Non-stereospecific dipeptidase
Non-stereospecific dipeptidase (, peptidyl-D-amino acid hydrolase, D-(or L-)aminoacyl-dipeptidase) is an enzyme.
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Prenalterol
Synthesis
Stereospecific
Prenalterol exhibits adrenergic agonist activity in spite of an interposed oxymethylene group. The stereospecific synthesis devised for this molecule relies on the fact that the side chain is very similar in oxidation state to that of a sugar.
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Dynamic stereochemistry
Stereochemistry is involved in:
stereospecific reactions
stereoselective or asymmetric reactions
racemisation processes
References
Carey, Francis
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Stereoselectivity
chemistry, stereoselectivity is the property of a chemical reaction in which a single reactant forms an unequal mixture of stereoisomers during a non-stereospecific creation of a new stereocenter or during a non-stereospecific transformation of a pre-existing one.
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3-Methylheptane
References
External links
Non-stereospecific oxidation of DL-3-methylheptane by aPseudomonas
Alkanes
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3-甲基庚烷
参考文献
外部链接
Non-stereospecific oxidation of DL-3-methylheptane by aPseudomonas
辛
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HSD17B14
dehydrogenase type 14 also known as 17β-HSD type 14 or 17βHSD14 is an enzyme that in humans is encoded by the HSD17B14 gene.
17βHSD14 catalyzes the stereospecific
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酒石酸脱氢酶
这种酶能催化以下酶促反应:
酒石酸 + NAD+ + CO2 草酰羟乙酸 + NADH + H+
酒石酸脱氢酶是一种具有立体特异性(stereospecific)的胞内酶(intracellular enzyme)。
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(R)-amidase
(R)-amidase (, R-stereospecific amidase, R-amidase) is an enzyme with systematic name (R)-piperazine-2-carboxamide amidohydrolase.
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Mandelonitrile lyase
Mechanism of action
HNLs are known to be stereospecific, giving the action of this enzyme a major advantage in effectively creating precursors essential The step mediated by these enzymes is essential to the synthesis of stereospecific bond formation in (R)-Salbutamol bronchodilators, (S)-amphetamines,
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Cannabidiolic acid synthase
Enzyme function
Cannabidiolic acid synthase catalyses the production of cannabidiolate predominantly from cannabigerolate by stereospecific oxidative
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