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prototropy

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prototropy
prototropy Chem. (prəʊˈtɒtrəpɪ, ˈprəʊtəʊtrɒpɪ) [f. proton + Gr. τροπή turn, turning.] Tautomerism in which the forms differ only in the position of a proton; migration of a proton from one part of a molecule to another.1923 T. M. Lowry in Jrnl. Chem. Soc. CXXIII. 828 Prototropy, or the reversible ch... Oxford English Dictionary
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Tautomer
Prototropy Prototropy is the most common form of tautomerism and refers to the relocation of a hydrogen atom. wikipedia.org
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protomer
protomer (ˈprəʊtəmə(r)) [ult. f. Gr. πρῶτος first + -mer.] 1. Chem. [f. proton or prototropy.] Any prototropic tautomer.1923 [see prototropy]. 1968 Jrnl. Amer. Chem. Soc. XC. 1575/2 Analysis of the protomer stabilities in terms of relative chemical binding energies is risky. 1979 C. Roussel et al. i... Oxford English Dictionary
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Azomethine ylide
Another way to form azomethine ylides from imines is by prototropy and by alkylation. wikipedia.org
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tautomerism
tautomerism Chem. (tɔːˈtɒmərɪz(ə)m) [f. Gr. ταὐτο- tauto- + µέρος part, after isomerism; rendering Ger. tautomerie (Laar 1885).] The property exhibited by certain organic compounds of behaving in different reactions as if they possessed two (or more) different constitutions, that is, as if the atoms... Oxford English Dictionary
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Thermodynamic versus kinetic reaction control
This was interpreted as a case in the field of anionotropy of the phenomenon, familiar in prototropy, of the distinction between kinetic and thermodynamic wikipedia.org
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