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phosphorolysis
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phosphorolysis
phosphorolysis Biochem. (fɒsfəˈrɒlɪsɪs) [f. phosphorus or phosphorylation + hydrolysis.] A form of hydrolysis in which a bond in an organic molecule is broken and an inorganic phosphate group becomes attached to one of the atoms previously linked.1937 Enzymologia II. 160 Phosphorolysis is an enzymic...
Oxford English Dictionary
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Phosphorolysis
Phosphorolysis is the cleavage of a compound in which inorganic phosphate is the attacking group. It is analogous to hydrolysis. The mechanism involves phosphorolysis.
See also
Phosphorylase
References
External links
Chemical processes
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phosphorylase
phosphorylase Biochem. (fɒsˈfɒrɪleɪz, -s, ˈfɒsfərɪleɪz, -s) [f. prec. + -ase.] An enzyme that introduces a phosphate group into an organic compound.1939 G. T. Cori et al. in Jrnl. Biol. Chem. CXXVII. 771 Various mammalian tissues..contain an enzyme which can be extracted with water and which forms g...
Oxford English Dictionary
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S-methyl-5'-thioinosine phosphorylase
-methylthioadenosine in Pseudomonas aeruginosa involves deamination to S-methyl-5'-thioinosine (EC 3.5.4.31, S-methyl-5'-thioadenosine deaminase) and phosphorolysis
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Xanthosine phosphorylase
These degradation reactions are reversible in vitro, however, phosphorolysis dominates in vivo. Although this reaction is reversible in vitro, phosphorolysis is dominant in vivo.
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adenylylation
adenylylation, n. Biochem. (əˌdɛnɪlaɪˈleɪʃən) [f. adenylic a. + -yl + -ation.] = *adenylation n.1967 Proc. Nat. Acad. Sci. LVIII. 648 The physiological significance of the adenylylation mechanism. 1969 Federation Proc. XXVIII. 467/2 (title) Enzymatic adenylylation of pyrophosphate by 3{p},5{p} cycli...
Oxford English Dictionary
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3-O-alpha-D-glucosyl-L-rhamnose phosphorylase
following chemical reaction
3-O-alpha-D-glucopyranosyl-L-rhamnopyranose + phosphate L-rhamnopyranose + beta-D-glucose 1-phosphate
In the reverse phosphorolysis
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N,N'-diacetylchitobiose phosphorylase
diacetylchitobiose + phosphate N-acetyl-D-glucosamine + N-acetyl-alpha-D-glucosamine 1-phosphate
The mechanism for this reaction is as follows the enzymatic phosphorolysis
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Reaction scheme of cellulose phosphorolysis. a ... - ResearchGate
Background: Cellulosic biomass, the earth's most abundant renewable resource, can be used as substrates for biomanufacturing biofuels or biochemicals via in vitro synthetic enzymatic biosystems in ...
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Tetrose
When tetrose diphosphate is bound to the enzyme, the active site of the enzyme is blocked; therefore phosphorolysis of G3P is unable to occur.
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Glucose cycle
A phosphate group breaks the bond between C 1 of a glucose ring and the O that connects it to the next(phosphorolysis).
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Jakub Karol Parnas
Together with Władysław Baranowski, he discovered the process of phosphorolysis.
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Glycogen
Glycogen is cleaved from the nonreducing ends of the chain by the enzyme glycogen phosphorylase to produce monomers of glucose-1-phosphate:
In vivo, phosphorolysis
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Glycogenolysis
Glycogen branches are catabolized by the sequential removal of glucose monomers via phosphorolysis, by the enzyme glycogen phosphorylase.
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Entner–Doudoroff pathway
Glucose may alternatively be formed from the phosphorolysis or hydrolysis of intracellular starch or glycogen.
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