ProphetesAI is thinking...
periodate
Answers
MindMap
Loading...
Sources
Periodate
Synthesis
Classically, periodate was most commonly produced in the form of sodium hydrogen periodate (). See also
Sodium periodate
Potassium periodate
Periodic acid
References
Periodates
wikipedia.org
en.wikipedia.org
Sodium periodate
Sodium periodate is an inorganic salt, composed of a sodium cation and the periodate anion. Preparation
Classically, periodate was most commonly produced in the form of sodium hydrogen periodate ().
wikipedia.org
en.wikipedia.org
Potassium periodate
Potassium periodate is an inorganic salt with the molecular formula KIO4. Chemical properties
Potassium periodate decomposes at 582 °C to form potassium iodate and oxygen.
wikipedia.org
en.wikipedia.org
per-iodate
periodate, per-iodate Chem. (pəˈraɪədeɪt) [See per- 5.] A salt of periodic acid. (In Pharmacy, short for calcium periodate, an antiseptic.) periodic acid-Schiff (Biol.), phr. used attrib. and absol. to designate a procedure for the detection of carbohydrates by first oxidizing them to polyaldehydes ...
Oxford English Dictionary
prophetes.ai
Lithium periodate
Lithium periodate is an inorganic compound of lithium, iodine, and oxygen with the chemical formula .
wikipedia.org
en.wikipedia.org
pyranoside
pyranoside Chem. (paɪər-, pɪˈrænəsaɪd) [f. prec. + -ide.] Any glycoside in the pyranose form.1932 Jrnl. Chem. Soc. 2254 Usually the product is also contaminated with small amounts of the corresponding pyranosides. 1934, 1966 [see furanoside]. 1970 R. W. McGilvery Biochem. xxviii. 715 Furanosides and...
Oxford English Dictionary
prophetes.ai
Periodatonickelates
The periodatonickelates are a series of anions and salts of nickel complexed to the periodate anion. The first periodatonickalates discovered were sodium nickel periodate (NaNiIO6·​0.5H2O) and potassium nickel periodate (KNiIO6·&ZeroWidthSpace
wikipedia.org
en.wikipedia.org
Thiirane
Oxidation of thiirane with periodate gives ethylene episulfoxide.
References
Episulfides
wikipedia.org
en.wikipedia.org
Iodate
Iodate shows no tendency to disproportionate to periodate and iodide, in contrast to the situation for chlorate. Iodate is reduced by sulfite:
Iodate oxidizes iodide:
Similarly, chlorate oxidizes iodide to iodate:
Iodate is also obtained by reducing a periodate
wikipedia.org
en.wikipedia.org
Periodic acid
Because the process requires vicinal diols, periodate oxidation is often used to selectively label the 3′-termini of RNA (ribose has vicinal diols) instead Other oxyacids
Periodate is part of a series of oxyacids in which iodine can assume oxidation states of −1, +1, +3, +5, or +7.
wikipedia.org
en.wikipedia.org
Prenalterol
Hydrolytic removal of the acetonide protecting groups followed by cleavage of the sugar with periodate gives aldehyde (4).
wikipedia.org
en.wikipedia.org
Sodium iodate
concentrated solution of sodium hydroxide or sodium carbonate:
3 I2 + 6 NaOH → NaIO3 + 5 NaI + 3 H2O
Reactions
Sodium iodate can be oxidized to sodium periodate
wikipedia.org
en.wikipedia.org
Malaprade reaction
organic chemistry, the Malaprade reaction or Malaprade oxidation is a glycol cleavage reaction in which a vicinal diol is oxidized by periodic acid or a periodate
wikipedia.org
en.wikipedia.org