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perchloric
perchloric, a. Chem. (pəˈklɔərɪk) [f. per-1 5 b + chloric.] In perchloric acid, hydrogen perchlorate, HClO4, the oxygen acid of chlorine containing more oxygen than chloric acid (HClO3).1818 W. Henry Elem. Chem. (ed. 8) I. 437 The per-chloric acid will then consist of one atom of chlorine = 33·5, un...
Oxford English Dictionary
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Perchloric acid
Perchloric acid is a mineral acid with the formula HClO4. Perchloric acid forms an azeotrope with water, consisting of about 72.5% perchloric acid.
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Indium perchlorate
The compound is an indium salt of perchloric acid. Synthesis
Dissolving indium hydroxide in perchloric acid:
In(OH)3 + 3HClO4 -> In(ClO4)3 + 3H2O
Physical properties
Indium(III) perchlorate forms colorless
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Yttrium perchlorate
The compound is an yttrium salt of perchloric acid. Synthesis
Dissolving yttrium oxide in perchloric acid solution can produce yttrium perchlorate octahydrate.
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Silver perchlorate
Production
Silver perchlorate is created by heating a mixture of perchloric acid with silver nitrate. Alternatively, it can be prepared by the reaction between barium perchlorate and silver sulfate, or from the reaction of perchloric acid with silver oxide
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Hydronium perchlorate
Production
Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio:
A more analytically reliable It can also be produced by the reaction of anhydrous nitric acid and perchloric acid.
References
Oxonium compounds
Perchlorates
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Rhodium(III) perchlorate
The compound is prepared by treating hydrated rhodium(III) chloride and perchloric acid at elevated temperatures:
[Rh(H2O)6]Cl3 + 3 HClO4 → [Rh(H2O )6](ClO4)3 + 3 HCl
The reaction of rhodium(III) hydroxide with concentrated perchloric acid also produce rhodium(III) perchlorate.
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Perchloratoborate
Reactions
When rubidium perchloratoborate is reacted with extra perchloric acid, it forms RbBO(ClO4)2. Another way is to react a metal chloridoborate (MBCl4) with perchloric acid.
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Dichlorine heptoxide
This chlorine oxide is the anhydride of perchloric acid. It slowly hydrolyzes back to perchloric acid.
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Lead(II) perchlorate
→ Pb(ClO4)2 + HNO3
The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
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Scandium perchlorate
Production
Scandium perchlorate can be prepared by dissolving scandium oxide in perchloric acid:
References
Scandium compounds
Perchlorates
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Dichlorine pentoxide
the perchloryl/chloride peroxide structure would be the most stable among various isomers, such as the anhydride of chloric acid or the chlorous acid/perchloric
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Terbium(III) perchlorate
This salt of terbium(III) can be obtained by reacting terbium(III,IV) oxide with perchloric acid.
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Nickel(II) perchlorate
The yellow anhydrous product is obtained by adding nickel(II) trifluoroacetate and perchloric acid in a trifluoroacetic acid solvent. See also
Nickel
Perchloric acid
References
Oxidizing agents
Nickel compounds
Perchlorates
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Copper(II) perchlorate
Copper(II) perchlorate is a salt of copper and perchloric acid.
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