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nitronium
nitronium Chem. (naɪˈtrəʊnɪəm) [mod.L. (coined in Ger. by A. Hantzsch 1925, in Ber. d. Deut. Chem. Ges. LVIII. 943): see nitro- and -onium.] † a. The cation which was supposed to be formed by ionization in pure nitric acid and formulated as [NO(OH)2]+ or [N(OH)3]2+. Obs.1925 Chem. Abstr. XIX. 2312 T...
Oxford English Dictionary
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Nitronium tetrafluoroborate
Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. Applications
Nitronium tetrafluoroborate is used as a nitration agent.
References
Tetrafluoroborates
Nitronium compounds
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Nitronium perchlorate
and the nitronium cation. Decomposition rate of nitronium perchlorate can be altered by doping with multivalent cations.
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-onium
-onium, suffix [abstracted from ammonium.] 1. Chem. Used in forming the names of complex cations that contain a more or less electronegative central atom, usu. bonded to a number of protons (or to other species that are regarded as substituents), as arsonium, carbonium, hydrazonium, nitronium, oxoni...
Oxford English Dictionary
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Nitrosonium
Nitronium is a more potent electrophile than is nitrosonium, as anticipated by the fact that the former is derived from a strong acid (nitric acid) and (C6Et6)Cr(CO)3 + NOBF4 → [(C6Et6)Cr(CO)2(NO)]BF4 + CO
See also
Nitronium (NO2+)
Nitric oxide (NO)
References
Oxycations
Nitrogen(III) compounds
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Nitrosyl perchlorate
It is highly oxidizable, and forms nitronium perchlorate when decomposed.
References
nitrosyl
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Nitryl cyanide
The reaction of nitronium tetrafluoroborate with tert-butyldimethylsilyl cyanide at −30 °C produces nitryl cyanide, with tert-butyldimethylsilyl fluoride
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Nitryl azide
It has been detected by infrared spectroscopy as a short-lived product of the reaction between sodium azide and nitronium hexafluoroantimonate:
The compound
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Nitratoauric acid
production of the simple nitrate (Au(NO3)3) was reported from the reaction of gold oxide and dinitrogen pentoxide, however, this was later proven to be nitronium
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NO2 (disambiguation)
NO2 may also refer to:
Nitrite ion, NO2−
Nitronium ion, NO2+
–NO2, nitro group, characteristic of nitro compounds
"NO2", a song by American rock band
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Tetraperchloratoaluminate
Formation
Nitronium tetraperchloratoaluminate is made from exact amounts of nitronium perchlorate and anhydrous aluminium chloride combined in liquid sulfur Ammonium tetraperchloratoaluminate can be formed by three moles of nitronium perchlorate, one mole of anhydrous aluminium chloride, and one mole of ammonium
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Nitrogen oxide
dimer
Dinitrogen trioxide (), nitrogen(II,IV) oxide
Dinitrogen tetroxide (), nitrogen(IV) oxide dimer
Dinitrogen pentoxide (), nitrogen(V) oxide, or nitronium Nitrosyl azide (), nitrogen(−I,0,I,II) oxide
Nitryl azide ()
Oxatetrazole ()
Trinitramide ( or ), nitrogen(0,IV) oxide
Anions
Cations
Nitrosonium ( or )
Nitronium
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Tetranitratoaluminate
Formation
When hydrated aluminium nitrate reacts with dinitrogen pentoxide it forms a nitronium salt: [NO2]+[Al(NO3)4]−. When nitronium tetranitratoaluminate is sublimed it can form anhydrous aluminium nitrate.
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Zirconium nitrate
A contaminating substance in this is nitronium pentanitratozirconate. (NO2)Zr(NO3)5. A mixed nitronium, nitrosonium pentanitratozirconate crystallizing in the tetragonal system also exists.
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Hexaperchloratoaluminate
To form hexaperchloratoaluminates, one can heat aluminium nitrate in the presence of nitrosonium or nitronium perchlorate at a temperature of 125 °C: studies, this compound can only be produced via a low-yielding synthesis route including the reaction of aluminium chloride, hydrazinium perchlorate, and nitronium
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