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Nephelauxetic effect - Wikipedia
It refers to a decrease in the Racah interelectronic repulsion parameter, given the symbol B, that occurs when a transition-metal free ion forms a complex with ... en.wikipedia.org
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20.9A: The Nephelauxetic Effect - Chemistry LibreTexts
The nephelauxetic effect refers to a decrease in the Racah interelectronic repulsion parameter that occurs when a transition-metal free ion ... chem.libretexts.org
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Nephelauxetic Effect - an overview | ScienceDirect Topics
The nephelauxetic effect refers to the expansion of the orbital formed by the overlap of metal and ligand orbitals during complex formation, resulting in ... www.sciencedirect.com
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nephelauxetic
nephelauxetic, a. Physical Chem. (nɛfəlɔːkˈsɛtɪk) [f. Gr. νεϕέλ-η cloud + αὐξητικ-ός auxetic a.] Causing an expansion of the d-electron cloud of a central atom, i.e. a decrease in the inter-electron repulsion parameter; nephelauxetic series, a series of ligands arranged in order of their nephelauxet... Oxford English Dictionary
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The Nephelauxetic Effect Becomes an Important Design Factor for ...
The expansion of d-orbitals as a result of metal-ligand bond covalence, the so-called nephelauxetic effect, is a well-established concept of ... onlinelibrary.wiley.com
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[PDF] Spectrochemical and Nephelauxetic Series - Dalal Institute
➢ The Nephelauxetic Series. The nephelauxetic series is a list of ligands or metal ions ordered on the basis of the strength of their nephelauxetic effect. www.dalalinstitute.com
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Nephelauxetic effect
The nephelauxetic effect is a term used in the inorganic chemistry of transition metals. the nephelauxetic parameter always follows a certain trend with respect to the nature of the ligands present. wikipedia.org
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What is nephelauxetic effect? - Quora
The nephelauxetic effect is a term used the inorganic chemistry of transition metals. It refers to a decrease in the Racah interelectronic ... www.quora.com
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The Nephelauxetic Effect Becomes an Important Design Factor for ...
The nephelauxetic effect can be a game changer regarding the photophysical properties of 3d metal complexes in solution at room temperature. pubmed.ncbi.nlm.nih.gov
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Exploring the Role of the Nephelauxetic Effect in Circularly ...
Comparison with structurally related homo- and heteroleptic chromium(III) complexes underscores the important role of the nephelauxetic effect in tuning CPL ... pubs.acs.org
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Nephelauxetic effect revisited - NASA ADS
We readdress the well-known nephelauxetic effect in coordination compounds of transition metal ions and analyze its possible origins presented in the ... ui.adsabs.harvard.edu
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Nephelauxetic effect and covalency of metal-ligand bonds
The Racah repulsion parameters are smaller in a transition metal complex than in a free atomic ion because. chemistry.stackexchange.com
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Racah parameter
See also Tanabe–Sugano diagram Nephelauxetic effect References External links Multiplets in Transition Metal Ions in E. Pavarini, E. Koch, F. wikipedia.org
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spectrochemical
spectrochemical, a. (spɛktrəʊˈkɛmɪkəl) [f. spectro- + chemical a.] Of or pertaining to spectrochemistry; spectrochemical series, a series of ligands arranged in order of magnitude of the ligand field splitting that they cause in the electronic orbitals of a central atom.1896 Jrnl. Chem. Soc. LXX. i.... Oxford English Dictionary
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Ligand field theory
'-bipyridine) < phen (1,10-phenanthroline) < NO2− < PPh3 < CN− < CO See also Crystal field theory Ligand dependent pathway Molecular orbital theory Nephelauxetic wikipedia.org
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