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nephelauxetic
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nephelauxetic
nephelauxetic, a. Physical Chem. (nɛfəlɔːkˈsɛtɪk) [f. Gr. νεϕέλ-η cloud + αὐξητικ-ός auxetic a.] Causing an expansion of the d-electron cloud of a central atom, i.e. a decrease in the inter-electron repulsion parameter; nephelauxetic series, a series of ligands arranged in order of their nephelauxet...
Oxford English Dictionary
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Nephelauxetic effect
The nephelauxetic effect is a term used in the inorganic chemistry of transition metals. the nephelauxetic parameter always follows a certain trend with respect to the nature of the ligands present.
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Racah parameter
See also
Tanabe–Sugano diagram
Nephelauxetic effect
References
External links
Multiplets in Transition Metal Ions in E. Pavarini, E. Koch, F.
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spectrochemical
spectrochemical, a. (spɛktrəʊˈkɛmɪkəl) [f. spectro- + chemical a.] Of or pertaining to spectrochemistry; spectrochemical series, a series of ligands arranged in order of magnitude of the ligand field splitting that they cause in the electronic orbitals of a central atom.1896 Jrnl. Chem. Soc. LXX. i....
Oxford English Dictionary
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Ligand field theory
'-bipyridine) < phen (1,10-phenanthroline) < NO2− < PPh3 < CN− < CO
See also
Crystal field theory
Ligand dependent pathway
Molecular orbital theory
Nephelauxetic
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series
series (ˈsɪəriːz, formerly ˈsɪərɪiːz) Pl. (8–) series, (7– 8, rare in 9) serieses, (7–8) series's. [a. L. seriēs row, chain, series, f. ser-ĕre to join, connect. Cf. F. série, It., Sp., Pg. serie.] I. General senses. 1. A number or set of material things of one kind ranged in a line, either contiguo...
Oxford English Dictionary
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