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mutarotation

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mutarotation
mutarotation Chem. (mjuːtərəˈteɪʃən) [f. L. mūtā-re to change + rotation.] The change of optical activity with time exhibited by the solutions of some compounds (esp. sugars) after being made up. (Orig. called multirotation (multi- 2).)1899 T. M. Lowry in Jrnl. Chem. Soc. LXXV. 213 The essential fea... Oxford English Dictionary
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Mutarotation
In stereochemistry, mutarotation is the change in optical rotation of a chiral material due to a change in equilibrium between the two constituent anomers Cyclic sugars show mutarotation as α and β anomeric forms interconvert. wikipedia.org
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birotation
birotation Physical Chem. (baɪrəˈteɪʃən) [bi-2.] The power possessed by certain sugars of changing their rate of optical rotation according to the length of time they have been in solution. Now usually called mutarotation.1882 Robb & Veley tr. Landolt's Handbk. Polariscope iv. 62 A peculiar case of ... Oxford English Dictionary
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Furanose
Typically, the anomeric carbon undergoes mutarotation in solution, and the result is an equilibrium mixture of α and β configurations. wikipedia.org
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erythrose
erythrose Chem. (ɛˈrɪθrəʊz, ˈɛrɪθrəʊz, -s) [f. erythrite + -ose2.] A tetrose sugar, CHO·[CH(OH)]2·CH2OH, isolated as a liquid and existing in two molecular configurations; it differs from threose in having the hydroxyl groups on the second and third carbon atoms on the same side of the carbon chain.... Oxford English Dictionary
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Maltose
Maltose in aqueous solution exhibits mutarotation, because the α and β isomers that are formed by the different conformations of the anomeric carbon have wikipedia.org
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Non-competitive inhibition
made significant contributions to enzyme kinetics during his doctoral thesis, however he lacked noting the importance of hydrogen ion concentration and mutarotation Although, these are both in the dextrorotatory form, this is where they noted that glucose can change spontaneously, also known as mutarotation. wikipedia.org
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polarization
polarization (pəʊləraɪˈzeɪʃən) [In sense 1, a. F. polarisation, n. of action f. polariser (both introduced by Malus, 11 March 1811): see polarize. In later uses, n. of action from the vb. in corresp. senses.] The condition or fact of being polarized; the action of polarizing. I. 1. a. A modification... Oxford English Dictionary
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N-acetylneuraminate epimerase
See also sialic acid N-acetylneuraminate Mutarotation References External links EC 5.1.3 wikipedia.org
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polarimeter
polarimeter (pəʊləˈrɪmɪtə(r)) [f. med.L. polāri-s polar (with reference to polarization) + -meter.] A form of polariscope for measuring the amount of rotation of the plane of polarization, or the amount of polarized light in a beam.1864 in Webster. 1869 Eng. Mech. 24 Dec. 357/3 The detection..may be... Oxford English Dictionary
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Sulfoglycolysis
Production of sulfoquinovose and its mutarotation Sulfoquinovose is rarely found in its free form in nature; rather it occurs predominantly as a glycoside wikipedia.org
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Sulfoquinovose
The half-life for mutarotation of sulfoquinovose at pD 7.5 and 26C is 299 minutes. wikipedia.org
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مالتوز
المالتوز في محلول مائي يعرض دوران تبدّلي (mutarotation)، لأن ايزوميرات α وβ التي يتم تشكيلها من خلال المطابقات المختلفة للكربون الشاذ  له دورات محددة مختلفة wikipedia.org
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Augustin-Pierre Dubrunfaut
Mutarotation was discovered by Dubrunfaut in 1844, when he noticed that the specific rotation of aqueous sugar solution changes with time. wikipedia.org
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Charles Joseph Tanret
He notably studied the chemistry of sugars, reporting his observations of the mutarotation of glucose in 1895. wikipedia.org
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