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imine
imine Chem. (ˈɪmiːn) [ad. G. imin (A. Ladenburg 1883, in Ber. d. Deut. Chem. Ges. XVI. 1150), formed by altering amin amine (cf. imide, amide).] Any compound containing the group {b2}NH (or the substituted form {b2}NR) attached to one carbon atom that forms part of a non-acidic organic group, or con... Oxford English Dictionary
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Imine
When R = H, the compound is a primary imine, when R is hydrocarbyl, the compound is a secondary imine. When R3 is OH, the imine is called an oxime, and when R3 is NH2 the imine is called a hydrazone. wikipedia.org
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Imines - Properties, Formation, Reactions, and Mechanisms
Mar 7, 2022Imines - Their Properties, Formation, Reactions, and Mechanisms. Imines are the nitrogen analogues of aldehydes and ketones, containing a C=N bond instead of a C=O bond.; They are formed through the addition of a primary amine to an aldehyde or ketone, kicking out a molecule of water (H 2 O) in the process.; In this post we show some examples of the synthesis of imines, walk through the ...
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Benzophenone imine
Benzophenone imine is an organic compound with the formula of (C6H5)2C=NH. imine can also be synthesized by addition of phenylmagnesium bromide to benzonitrile followed by careful hydrolysis (lest the imine be hydrolyzed): wikipedia.org
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Methylene imine
Methylene imine is an organic compound with the formula . The simplest imine, it is a stable, colorless gas that has been detected throughout the universe. wikipedia.org
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Acetone imine
Acetone imine, or 2-propanimine is an organic compound and an imine with the chemical formula (CH3)2CNH. The imine of hexafluoroacetone, ((CF3)2C=NH) is by contrast robust. References Imines wikipedia.org
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N-Sulfinyl imine
N-Sulfinyl imines (N-sulfinylimines, sulfinimines, thiooxime S-oxides) are a class of imines bearing a sulfinyl group attached to nitrogen. These imines display useful stereoselectivity reactivity and due to the presence of the chiral electron withdrawing N-sulfinyl group. They allow 1,2-addition of... wikipedia.org
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Sydnone imine
Sydnone imine is a mesoionic heterocyclic aromatic chemical compound. Sydnone imine is the imine of sydnone where the keto functional group of sydnone (=O) has been replaced with an imine (=NH) group. wikipedia.org
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Imine Diels–Alder reaction
The imine Diels–Alder reaction involves the transformation of all-carbon dienes and imine dienophiles into tetrahydropyridines. nitrogen increases the reactivity of the imine. wikipedia.org
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Ojima lactam
The reaction centers around an imine - lithium enolate cycloaddition. The imine synthesis is a reaction of hexamethyldisilazane with phenyllithium to a strong amide base followed by a condensation reaction with benzaldehyde wikipedia.org
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Betti reaction
Mechanism The reaction mechanism begins with an imine condensation of a primary aromatic amine and formaldehyde Once the imine is produced, it reacts First, the lone-pair on the nitrogen of the imine deprotonates the phenol, pushing the bonding electrons onto the oxygen. wikipedia.org
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Hexamethylenediimine
The molecule is a diimine, consisting of a hexamethylene hydrocarbon chain terminated with imine functional groups. It is the result of the imine Formation, or alkylimino-de-oxo-bisubstitution, of hexamethylenediamine. References Imines wikipedia.org
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Aza-Diels–Alder reaction
The imine is often generated in situ from an amine and formaldehyde. See also Oxo Diels–Alder reaction Imine Diels–Alder reaction References Cycloadditions Nitrogen heterocycle forming reactions Name reactions wikipedia.org
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Mannich base
Mannich reaction, which is nucleophilic addition reaction of a non-enolizable aldehyde and any primary or secondary amine to produce resonance stabilized imine (iminium ion or imine salt). wikipedia.org
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Staudinger synthesis
The Staudinger synthesis, also called the Staudinger ketene-imine cycloaddition, is a chemical synthesis in which an imine 1 reacts with a ketene 2 through Other factors that affect the stereochemistry include the initial regiochemistry of the imine. wikipedia.org
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