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hydroxylamine
hydroxylamine Chem. (haɪˈdrɒksɪləˌmaɪn) [f. prec. + amine.] A basic substance, NH2OH, allied to ammonia, which combines with acids to form a well-defined series of salts. Discovered in 1865 by Lossen, but until 1891 known only in its salts or in aqueous solution.1869 Roscoe Elem. Chem. 216 Hydroxyla...
Oxford English Dictionary
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Hydroxylamine
Hydroxylamine oxidoreductase (HAO) further oxidizes hydroxylamine to nitrite. (preparation of hydroxylamine-O-sulfonic acid).
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Hydroxylamine oxidoreductase
Hydroxylamine oxidoreductase (HAO) is an enzyme found in the prokaryotic genus Nitrosomonas. The substrate is hydroxylamine (NH2OH), a chemical produced biologically by the enzyme Ammonia monooxygenase.
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Hydroxylamine dehydrogenase
Hydroxylamine dehydrogenase (, HAO (ambiguous)) is an enzyme with systematic name hydroxylamine:ferricytochrome-c oxidoreductase. This enzyme catalyses the following chemical reaction
(1) hydroxylamine + H2O + 2 ferricytochrome c nitrite + 2 ferrocytochrome c + 5 H+
(2) hydroxylamine
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Hydroxylamine-O-sulfonic acid
hydroxylamine with oleum. Diimine can formed in situ from hydroxylamine-O-sulfonic acid respectively hydroxylamine-O-sulfonic acid hydroxylamine sulfate mixtures, which hydrogenates
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Hydroxylamine reductase
In enzymology, a hydroxylamine reductase () is an enzyme that catalyzes the chemical reaction
NH3 + H2O + acceptor hydroxylamine + reduced acceptor Other names in common use include hydroxylamine (acceptor) reductase, and ammonia:(acceptor) oxidoreductase.
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Hydroxylamine reductase (NADH)
NH3 + NAD+ + H2O hydroxylamine + NADH + H+
The 3 substrates of this enzyme are NH3, NAD+, and H2O, whereas its 3 products are hydroxylamine, NADH, and Other names in common use include hydroxylamine reductase, ammonium dehydrogenase, NADH-hydroxylamine reductase, N-hydroxy amine reductase, hydroxylamine
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羟胺
参见
联氨
参考资料
Hydroxylamine
Walters, Michael A. and Andrew B. Hoem. "Hydroxylamine." e-Encyclopedia of Reagents for Organic Synthesis. 2001. (preparation of hydroxylamine-O-sulfonic acid).
外部链接
羟胺的分解反应研究
MSDS
Q
无机胺
氢氧化物
照相药品
火箭燃料
还原剂
羟胺
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Hydroxylammonium sulfate
Hydroxylammonium sulfate (NH3OH)2SO4, is the sulfuric acid salt of hydroxylamine. This initially gives hydroxylamine disulfonate, which is hydrolysed to hydroxylammonium sulfate:
It can also be obtained by the acid-base reaction of hydroxylamine
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Aromatic-hydroxylamine O-acetyltransferase
In enzymology, an aromatic-hydroxylamine O-acetyltransferase () is an enzyme that catalyzes the chemical reaction
N-hydroxy-4-acetylaminobiphenyl + N-hydroxy Other names in common use include aromatic hydroxylamine acetyltransferase, arylhydroxamate acyltransferase, arylhydroxamate N,O-acetyltransferase, arylhydroxamic
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胲
如果烃基连接至氧原子处,就叫氧胲(O-hydroxylamine),而连接至氮原子处,就叫氮胲(N-hydroxylamine)。氧胲的通式是NH2O-R,而氮胲的通式可以是R-NOH或者RR'NOH。如果所有氢原子被取代,就会是RR'NOR。 来源
有机化合物
氧化合物
氢化合物
氮化合物
碳化物
en:Hydroxylamine#Functional group
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N,O-Dimethylhydroxylamine
N,O-Dimethylhydroxylamine is a methylated hydroxylamine used to form so called 'Weinreb amides' for use in the Weinreb ketone synthesis. Synthesis
It may be prepared by reacting ethyl chloroformate (or similar) with hydroxylamine followed by treatment with a methylating agent such as dimethyl
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Methoxyamine
It is a derivative of hydroxylamine with the hydroxyl hydrogen replaced by a methyl group. Synthesis
Methoxyamine is prepared via O-alkylation of hydroxylamine derivatives.
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Ammonia monooxygenase
Aerobic oxidation of ammonia to hydroxylamine via AMO is an endergonic reaction. It was believed that aerobic ammonia-oxidizing bacteria oxidize hydroxylamine to nitrite using octahaem hydroxylamine oxidoreductase (HAO).
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Aspartyltransferase
Thus, the two substrates of this enzyme are L-asparagine and hydroxylamine, whereas its two products are NH3 and L-aspartylhydroxamate. The systematic name of this enzyme class is L-asparagine:hydroxylamine gamma-aspartyltransferase.
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