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cacodyl
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cacodyl
cacodyl Chem. (ˈkækəʊdɪl) Also kakodyl(e. [f. Gr. κακώδ-ης stinking, κακωδία stink (f. κακό-ς + ὀδ-, root of ὄζειν to emit smell) + -yl, matter.] An organic compound of arsenic and methyl, As(CH3)2 = Kd, also called arsendimethyl, a colourless liquid, of most disgusting garlic odour and with extreme...
Oxford English Dictionary
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Cacodyl
Cacodyl undergoes spontaneous combustion in dry air.
Cacodyl is also the name of the functional group or radical (CH3)2As. From it other compounds were made, such as cacodyl fluoride, cacodyl chloride, et cetera. One compound, cacodyl cyanide, was particularly awful.
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Cacodyl cyanide
Cacodyl cyanide is a highly toxic organoarsenic compound discovered by Robert Bunsen in the 1840s. Synthesis
Cacodyl cyanide can be prepared by reaction of cacodyl oxide with hydrogen cyanide or mercuric cyanide.
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is dicacodyl poisonous
Cacodyl is an organoarsenic compound that constitutes a major part of "Cadet's fuming liquid" It is a poisonous oily liquid with an extremely unpleasant
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Cacodyl oxide
Cacodyl oxide is a chemical compound of the formula [(CH3)2As]2O. See also
Arsenic
Arsine
Cacodylic acid
Lewisite
Cacodyl cyanide
References
Cacodyl compounds
Foul-smelling chemicals
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en.wikipedia.org
cacodylic
cacodylic, a. Chem. (kækəʊˈdɪlɪk) [f. cacodyl + -ic.] Of cacodyl, as in cacodylic acid, Kd O2H, a crystalline solid.1850 C. G. B. Daubeny Atomic Theory vii. 219 Kd + O3 forms kakodylic acid, or algargen. 1869 Roscoe Elem. Chem. 341 One of the most important compounds is cacodylic acid; it is soluble...
Oxford English Dictionary
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Cacodylic acid
oxide, and cacodyl, . Cacodyl oxide, , is often considered the first organometallic compound to be prepared synthetically.
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dysodyle
dysodyle, -ile Min. (ˈdɪsəʊdaɪl) [a. F. dysodyle (Cordier 1808) f. Gr. δυσώδης ill-smelling, stinking + ὕλη matter: cf. cacodyl.] A very inflammable hydrocarbon occurring in masses of a yellowish or greenish colour, and foliated structure, which emits a fetid odour when burned.1809 Nicholson's Jrnl....
Oxford English Dictionary
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Louis Claude Cadet de Gassicourt
This liquid is known as Cadet's fuming liquid and contains the two compounds cacodyl and cacodyl oxide.
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alkarsin
alkarsin Chem. (ælˈkɑːsɪn) [f. alkali) + arsenic) + -in, in reference to its preparation.] A heavy poisonous liquid, spontaneously inflammable, with disgusting odour of garlic, formed by distillation of arsenious oxide and dry acetate of potash, supposed to be a variable mixture of cacodyl and its o...
Oxford English Dictionary
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1,2-Bis(dimethylarsino)benzene
References
Benzene derivatives
Chelating agents
Cacodyl compounds
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联二甲胂
形成氧化物的反应类似于:
后来开发了一种更好的合成方法,从一氯甲胂和二甲胂开始:
历史
罗伯特·威廉·本生为二甲胂基自由基(CH3)2As创造了名称kakodyl(后来在英语中修改为cacodyl),来自希腊语κακώδης(“kakōdēs”,“恶臭”)和 ὕλη(“hylē”,“物质”)。
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Cadet's fuming liquid
It consisted mostly of dicacodyl (((CH3)2As)2) and cacodyl oxide (((CH3)2As)2O).
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Dimethyl(trifluoromethylthio)arsine
See also
Cacodyl
Cacodyl cyanide
Diphenylchlorarsine
Lewisite
Methyldichloroarsine
Tetrachlorodinitroethane
Bis(trifluoromethyl) disulfide
References Arsenical vesicants
Arsenic(III) compounds
Vomiting agents
Trifluoromethylthio compounds
Cacodyl compounds
wikipedia.org
en.wikipedia.org
Diphenylcyanoarsine
See also
Cacodyl cyanide
Clark 1
Chemical weapons
References
Chemical weapons
Vomiting agents
Organoarsenic compounds
Pulmonary agents
Phenyl compounds
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en.wikipedia.org