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borane
borane Chem. (ˈbɔəreɪn) [ad. G. boran (A. Stock 1916, in Ber. d. Deut. Chem. Ges. XLIX. 111), f. boron + -ane (after methane, etc.).] The systematic name for a boron hydride; spec. the (hypothetical) compound BH3; also, any substituted derivative of a boron hydride.1916 Jrnl. Chem. Soc. Abstr. CX. i...
Oxford English Dictionary
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Borane
borane molecule. Borane dimethylsulfide which is more stable than borane–tetrahydrofuran may also be used.
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Borane–tetrahydrofuran
Borane–tetrahydrofuran is an adduct derived from borane and tetrahydrofuran (THF). See also
Ammonia borane
Borane dimethylsulfide
Borane tert-butylamine
References
Boranes
Reagents for organic chemistry
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diborane
diborane Chem. (daɪˈbɔəreɪn) [f. di-2 + borane.] A borane containing two atoms of boron; spec. B2H6, a colourless poisonous gas having a disagreeable odour.1926 Brit. Chem. Abstr. 227/2 Structure of ethane and diborane, B2H6. 1956 Chem. & Engin. News 6 Feb. 560/2 The names of some of the boron hydri...
Oxford English Dictionary
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Borane dimethylsulfide
Borane dimethylsulfide (BMS) is a chemical compound with the chemical formula . The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran, are its increased stability and higher solubility.
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Alpine borane
Alpine borane is the commercial name for an organoboron compound that is used in organic synthesis. Related reagents
A range of alkyl-substituted borane are specialty reagents in organic synthesis.
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Borane carbonyl
Borane carbonyl is the inorganic compound with the formula . This colorless gas is the adduct of borane and carbon monoxide. Structure and properties
The structure of the molecule of borane carbonyl is . The linkage is linear.
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Phosphine-borane
nHnPBH3
Because borane solutions are expensive or dangerous, the borane is often generated in situ, e.g., by oxidation of borohydride with iodine. is often tris(pentafluorophenyl)borane
Ammonia borane, related to phosphine-borane but with ammonia or amines in place of organophosphines
References
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Tris(pentafluorophenyl)borane
Structure
The structure of tris(pentafluorophenyl)borane (BCF) was determined by gas electron diffraction. The resulting cationic zirconocene species is stabilised by the non coordinating borane anion.
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BMS
BMS可以指:
动作感知系统 - (Body Motion Sensors)
甲硫醚硼烷 - (Borane dimethylsulfide)
波音海上系统
百时美施贵宝 - (Bristol-Myers Squibb),美国制药公司集团。
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Ammonia borane
()
Borane isopropylamine ()
The first amine adduct of borane was derived from trimethylamine. See also
Phosphine-borane ()
borane dimethylsulfide ()
borane–tetrahydrofuran ()
References
Inorganic compounds
Boranes
Boron–nitrogen compounds
Inorganic
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Borane tert-butylamine
Borane tert-butylamine is an amine borane complex derived from tert-butylamine and borane. It is a colorless solid. See also
Ammonia borane
References
Boranes
Boron–nitrogen compounds
Reagents for organic chemistry
Tert-butyl compounds
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Boranes
For example, reaction of a borane cluster with B2H6 (as a source of BH3) can lead to the formation of a conjuncto-borane species in which borane cluster Applications
Diborane and its monomeric adducts borane–tetrahydrofuran or borane–dimethylsulfide are useful reagents.
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Disiamylborane
Disiamylborane (bis(1,2-dimethylpropyl)borane, Sia2BH) is an organoborane used in organic synthesis. Thexylborane ((1,1,2-trimethylpropyl)borane, ThxBH2), a primary borane obtained by hydroboration of tetramethylethylene.
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Octadecaborane
This compound was the first borane found to have multiple isomeric forms. Among the geometric isomers, one with chirality was the first borane to be resolved into its separate enantiomers, and was only the second chiral borane
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