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acrolein
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acrolein
acrolein (əˈkrəʊliːɪn) [f. L. acr-is sharp, pungent + olē-re to smell + -ine = Gr. -ινη daughter, derivative; here used to form a term analogous to glycerin.] A colourless acrid liquid, of pungent irritating odour, formed in the destructive distillation of glycerin (from which it is derived by the a...
Oxford English Dictionary
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Acrolein
The acrolein content in cigarette smoke depends on the type of cigarette and added glycerin, making up to 220 µg acrolein per cigarette. Microbe-produced reuterin is a potential resource of acrolein.
Analytical methods
The "acrolein test" is for the presence of glycerin or fats.
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acryl
acryl Chem. (ˈækrɪl) [f. acrolein + -yle = Gr. ὕλη substance, stuff.] The hypothetical oxidized radical of the allyl series, C3H3O, formed from allyl by the substitution of an atom of oxygen for two of hydrogen; a constituent of acrolein and acrylic acid.
Oxford English Dictionary
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Reuterin
Besides, 3-hydroxypropionaldehyde suffers an spontaneous dehydration in aqueous solution, and the resulting molecule is called acrolein. This last molecule, acrolein, was recently included in reuterin definition.
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disacryl
disacryl Chem. (dɪsˈækrɪl) [f. dis- (implying disintegration or dissolution) + acryl.] A white flocculent substance into which acrolein changes when kept for some time. Called also disacrone. Also attrib., as disacryl resin, a resinous matter similarly formed.1863–72 Watts Dict. Chem. II. 336 Acrole...
Oxford English Dictionary
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Acroleinide
In organic chemistry, acroleinide is a functional group which is composed of a cyclic ketal of a diol with acrolein.
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allylic
allylic, a. Chem. (əˈlɪlɪk) [f. allyl + -ic.] Of or belonging to allyl.1857 W. A. Miller Elem. Chem. iii. vi. §2. 386 Hofmann and Cahours have succeeded in discovering the allylic..alcohol.., a compound which stands in the same relation to acrolein that ethylic alcohol does to ordinary aldehyd. 1863...
Oxford English Dictionary
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Oxiranol
compound has been proposed as an intermediate in the interstellar formation of glycolaldehyde (a constitutional isomer of oxiranol) and the oxidation of acrolein
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Oxetene
Synthesis
Oxetene can be synthesised by the photochemical cyclization of acrolein:
References
Oxygen heterocycles
Four-membered rings
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Myrcenol
As a 1,3-diene, myrcenol undergoes Diels-Alder reactions with several dienophiles such as acrolein to give cyclohexene derivatives that are also useful
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Mesna
These two anticancer agents, in vivo, may be converted to urotoxic metabolites, such as acrolein. acrolein and other urotoxic metabolites.
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Charles Moureu
During the war, he researched acrolein and sulfur mustard gas, working with Charles Dufraisse. Their work led to the use of acrolein and later benzyl iodide in weapons.
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2-Hydroxy-4-(methylthio)butyric acid
The compound is produced commercially in racemic form from acrolein by conjugate addition of methanethiol followed by formation and hydrolysis of a cyanohydrin
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M1G
The M1dG adduct in turn is formed by a condensation reaction between guanosine nucleotides in DNA and either malondialdehyde (propanedial) or acrolein Malondialdehyde is an end product of lipid peroxidation while acrolein is a result of DNA peroxidation.
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Chichibabin pyridine synthesis
500 °C. 2-Methylpyridine- and 4-methylpyridine are produced as a mixture from acetaldehyde and ammonia. 3-Methylpyridine and pyridine are produced from acrolein Acrolein and propionaldehyde react with ammonia affords mainly 3-methylpyridine. 5-Ethyl-2-methylpyridine is produced from paraldehyde and ammonia.
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