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Decalin
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Decalin
Isomers
Decalin occurs in cis and trans forms. Occurrence
Decalin itself is rare in nature but several decalin derivatives are known. They arise via terpene-derived precursors or polyketides.
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Decalin
Decalin (ˈdɛkəlɪn) Also Dekalin. [Trade mark in the U.S.] = decahydronaphthalene.1920 Chem. Abstr. XIV. 1227 New turpentine substitutes..Dekalin, C10H18... In the trade dekalin is not found pure, but always contains tetralin and is handled under the name tetralin extra. 1943 Thorpe's Dict. Appl. Che...
Oxford English Dictionary
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Maklamicin
motif. 1,3-bisphosphoglycerate is converted to glyceryl S-ACP and condenses onto the decalin-bearing polyketide intermediate to furnish an intermediate The intermediate, now containing both the tetronate and trans-decalin motifs of Maklamicin is then systematically reduced to afford a diene.
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Tetralin
Tetralin (ˈtɛtrəlɪn) Also tetralin. [f. tetra- + naphthaline.] = tetrahydronaphthalene s.v. tetra- 2 a. (A proprietary name in the U.S.)1920, etc. [see Decalin]. 1924 Nature 14 June 866/2 Excluding benzol..alternative fuels of greatest promise include ‘tetralin’ (tetrahydronaphthalene), which, mixed...
Oxford English Dictionary
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decahydronaphthalene
decahydroˈnaphthalene Chem. Also deka-. [f. deca- + hydro- + naphthalene.] A colourless liquid, C10H18, much used in the paint industry as a solvent, with a molecular structure consisting of two fused saturated rings; cf. Decalin.1877 Jrnl. Chem. Soc. ii. 899 Tetrahydroisoxylene absorbs oxygen, whil...
Oxford English Dictionary
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Tetralin
Over-hydrogenation converts tetralin into decahydronaphthalene (decalin). Rarely encountered is dihydronaphthalene (dialin).
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Perfluorodecalin
Perfluorodecalin () is a fluorocarbon, a derivative of decalin in which all of the hydrogen atoms are replaced by fluorine atoms. Manufacture
It is manufactured by the fluorination of tetralin or decalin with cobalt(III) fluoride in the Fowler process.
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Chlorotonil A
There is a spontaneous, non-enzymatic intramolecular Diels-Alder-like [4+2] cycloaddition at module 8 to furnish the decalin motif.
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Conipyridoin E
This tetramic acid moiety, along with the decalin structure, are key pharmacophores for antibiotic activity, as seen in a number of other decalin-containing These final modifications to the decalin and tetramate structures yield Conipyridoin E.
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Twistane
A 1967 publication concerned an intramolecular aldol condensation of a cis-decalin diketone. It is formed when basketane is hydrogenated.
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Sebacic acid
It can also be obtained from decalin via the tertiary hydroperoxide, which gives cyclodecenone, a precursor to sebacic acid.
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Clerodane diterpene
They are bicyclic terpenes that contain 20 carbons and a decalin core. diterpenes are classified into four groups trans-cis (TC), trans-trans (TT), cis-cis (CC), and cis-trans (TC) based on the relative stereochemistry at the decalin
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Bromocyclohexane
A mixture of cis-decalin and CXB can simultaneously match optical index and density of PMMA.
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Étard reaction
Another example arises from the Étard reaction of trans-decalin which results in a mixture of trans-9-decalol, spiro [4.5]decan-6-one, trans-1-decalone
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