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periostracum

periostracum Zool.
  (pɛrɪˈɒstrəkəm)
  [mod.L., f. Gr. περί around + ὄστρακον shell of a mussel, etc.]
  The outer horny covering of the shell of a mollusc or brachiopod. Hence periˈostracal a., pertaining to the periostracum.

1840 Penny Cycl. XVII. 452/1. 1841 Ibid. XXI. 373/1 The external coat or layer, Epidermis and Periostracum of authors, is of a somewhat horny or membranaceous character. 1870 Nicholson Man. Zool. 230 All living shells have an outer layer of animal matter, which is known as the ‘epidermis’, or ‘periostracum’.

Oxford English Dictionary

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