Each of the answers is obtained from the fact that the probability of the event in question the the complement of the given event. So in a), "at most one" is the complement of "at least two". So the prob. Of "at least two" is equal to $1-$ the prob of "at most one". Same reasoning goes for b): "at least one of each" is the prob of "all of one type". Here you have to add both possibilities given.