Your intuition is that each card has an equal probability of being chosen, and this is true. Yet you must consider that the cards have an not so equal probability of being chosen _and_ showing their red side.
Instead, observe that if I select a card, then select a side to show, both choices without bias, then _every side_ has an equal probability of being the one shown.
Now, when given that the side shown is red, the three _red sides_ still have equal probability of being that one shown. However only of them have a red otherside. The third red side has a green otherside.
Therefore there must be a conditional probability of $2/3$ for the otherside of the side shown to be red _when given_ that the side shown is itself red.