Just been given this formula by a colleague and it seems to work fine. I'll mark it as an answer for now and it may be useful for someone else in future. If (h) is the heading offset (clockwise rotation) of the daughter ship from the mother ship about the Z axis (alpha in the linked image), (r) is the roll of the mother ship and (p) is the pitch of the mother ship, then;
Daughter ship Roll = $-arcsin(cos(h+90)*sin(p)-sin(h+90)*sin(r))$
Daughter ship Pitch = $arcsin(cos(h)*sin(p)-sin(h)*sin(r))$