Ok, I am just going to write this out for completeness's sake.
You are given that
$$v_0 = 0$$
since you are told that the pilot begins from rest. You are then told that he experiences constant acceleration of 5.00 g (since we are dealing with m/s and not ft/s, g = 9.81). Now, using the exact equation from the problem, we can write
$$a = \Delta v/\Delta t = ((v_f - v_0)/\Delta t)$$
Plugging in results in:
$$5.00(9.81) = ((v_f - 0)/(5.00))$$
Which leaves you with a final velocity of $$v_f = 245.25 m/s$$ or, if you are particular about significant digits, $$v_f=245 m/s$$
Notice that this is actually less than Mach one, ultimately suggesting that human beings weren't meant to endure accelerations of 5 g's.