Since $R(3,3)=6$ there is a monochromatic triangle $\Delta$. Let's say it's blue. Look at the other three vertices. If there is no red edge between them then we've found a second blue triangle, so suppose we have found a red edge $xy$, $x,y\
otin\Delta$. If there are two blue edges from $x$ to $\Delta$ then we've found a second blue triangle, so assume there are two red edges from $x$ to $\Delta$. Similarly assume there are two red edges from $y$ to $\Delta$. But that means that there is a $z\in\Delta$ such that $xz$ and $yz$ are both red, so we've found a red triangle.