Note that L’Hopital rule is used only for limits of $\frac00$ or $\frac{\infty}{\infty}$ form.
Right now, on substituting $x=0$, we get a $\frac00$ form. But, if we differentiate it once, we get: $$\lim_{x \to 0} \frac{e^x}{3x^2}$$ which is **not of** $\frac00$ form. So, we **cannot use L’Hopital rule** here.
Evaluating the above limit, the answer is obviously $\infty$.