Your answer is correct, it is essentially $\frac{\binom{2}{1}\binom{10}{4}}{\binom{12}{5}} = \frac{35}{66}$, where you choose one of the captain/vice-captain group and 4 from the others.
To verify this we can compute the other probabilities as well:
both are chosen with probability $\frac{\binom{2}{2}\binom{10}{3}}{\binom{12}{5}} = \frac{5}{33} = \frac{10}{66}$, whereas none are chosen with probability $\frac{\binom{2}{0}\binom{10}{5}}{\binom{12}{5}} = \frac{7}{22} = \frac{21}{66}$ and all these nicely sum up to 1.