Yes, that is right. The boundary of the annulus between the two concentric circles is the union of the two circles, and the natural orientation is such that the outer circle is positively oriented, and the inner circle negatively, so
$$\int_{r < \lvert (x,y)\rvert < R} \operatorname{curl} F \,dS = \int_{\lvert (x,y)\rvert = R} F\cdot d\vec{s} - \int_{\lvert (x,y)\rvert = r} F\cdot d\vec{s}.$$