We have $64$ cells:
* $36$ cells have $4$ neighbors each
* $24$ cells have $3$ neighbors each
* $ 4$ cells have $2$ neighbors each
The total number of ways to choose $2$ out of $64$ cells is $\binom{64}{2}=2016$.
The number of ways to choose $2$ adjacent cells is $\frac{36\cdot4+24\cdot3+4\cdot2}{2!}=112$.
So the probability of choosing $2$ adjacent cells is $\frac{112}{2016}=\frac{1}{18}$.