This is easier to see if you extend the experiment and pick a coin and flip it say $100$ times. You would expect output like:
$$HT_uTTTT_uHTT_uHT\dots THHT$$
with a probability table:
$$ \begin{array} {c|c} H&0.25\\\ T_u&0.25\\\ T&0.5 \end{array} $$
If you throw a tails, $2/3$ times it will come from the biased coin, so if you say 'biased' every time tails appear, you will be right $2/3$ times.