The probability of a dice not showing 5 or 6 is $\frac{4}{6} = \frac{2}{3}$. Therefore the probability of not having any of the dice showing 5 of 6 is $\frac{2}{3}^3$. So the probabiliity of at least one die showing 5 or 6 is $1 - \frac{2}{3}^3$.
For $n$ dice this probability generalises to $1 - \frac{2}{3}^n$. The more dice you have, the larger this probability.