The `softvol` controls are stored in memory together with other data related to the actual sound card, and are saved to and restored from `/var/lib/alsa/asound.state` when the machine is shutting down or booting.
So to remove them, you have to
1. unload the sound driver module (`rmmod snd-hda-intel`, or whatever you're using), and then
2. remove the entry from `/var/lib/alsa/asound.state` (or the entire file).