This is an example, but it wasn’t picked out of thin air: `marc` is Marc Ewing, who created Red Hat Linux and wrote the initial version of the `/etc/aliases` file which ends up in CentOS.
The line is commented out, so it doesn’t have any effect; if you want to redirect email sent to root, it’s up to you to choose whatever recipient is appropriate, correct the line to take that into account, and uncomment it.