仕掛けてきてた in this context In this context, would in be: 1. to start; to begin; to commence​ or 2. to challenge; to pick (a fight); to make (war) ![Scene from the manga](

It's closer to 2, except that what the guy tried to start with her was not a fight or a war. can be used with anything that makes the other person upset or excited. "Your face was tempting me already!"

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