Given a topological space ($X$,$\tau$) and a subset $S$ of $X$, an point $x\in X$ is an accumulation point of $S$ if $$\forall U\in\tau(x),\exists s\in S, s\
eq x\land s\in U,$$ i.e, every open neighborhood of $x$ (I denote $\tau(x)$ by the set of open neighborhoods of $x$) contains a point of $S$ **different** than $x$.
Now, the indiscrete topology on $X$ is $\tau=\\{\emptyset,X\\}$. Let $A\subset X$ s.t $|A|=1$, i.e, $A=\\{a\\}$ for some $a\in X$.
According to the definition, $a$ is not an accumulation point of $A$, because there's no point in $A$ besides $a$, so you can't find points of $A$ **different** than $a$ in any open neighborhood of $a$. This shows that $A'\subset X\backslash\\{a\\}=X\backslash A$. ($A'$ is called derived set)). Then since we're working in the indiscrete topology, you have $X\backslash A\subset A'$ as well, hence $A'=X\backslash A$.