The moment generating function $f:t\mapsto E[e^{t X}]$ is convex, so its graph lies above all its tangent lines, including the one tangent at $(0,f(0))$. In particular $f(\theta)\ge f(0)+f'(0)\theta$. The mgf also has the property that its derivatives, evaluated at $0$, are the moments of $X$, so that $E[X^k] = f^{(k)}(0)$: that's why its called the _moment_ generating function. But we know $f(0)=1$ and are told that $f(\theta)=1$ and that $E[X]<0$. Put these together and we have $1\ge 1+ f'(0)\theta = 1+E[X]\theta$ and so $0\ge E[X]\theta.$ This implies $\theta\ge0$.
For example, suppose $X\sim N(-1,1)$, for which $E[X]<0$ and whose mgf is $$f(t)=E[\exp(tX)]=\exp(t^2/2-t)=\exp((t-1)^2/2-1/2).$$ There are two values of $\theta$ such that $f(\theta)=1$, namely $\theta=1\pm1$, that is, $0$ or $2$. Of these, the value of $\theta$ for which $\theta\
e0$ is $\theta=2$, which is positive.