The definition must be rephrased as :
> there are **no** truth assignment $A$ such that : $A(\psi)=1$ for every $\psi \in \Gamma$ and $A(\varphi)=0$.
Thus, what happens with a truth assignment $A'$ that assigns "false" (i.e. $0$) to some premise $\psi \in \Gamma$ ?
It doesn't matter what they "do" to $\varphi$, because we are only concerned with the truth assignements that "satisfy" (i.e. assign $1$) to **all** $\psi \in \Gamma$.
* * *
You must read the definition as a "recipe" to test for _entailment_ :
_(i)_ consider a truth assignement $A$ : are all formulae $\psi$ in $\Gamma$ _true_ for $A$ ?
* If NO, skip it (i.e. skip $A$).
* If YES, then check if $\varphi$ is true.
_(ii)_ if $\varphi$ is true for $A$, then take a new truth assignment $A'$ and go to step _(i)_.
_(iii)_ if $\varphi$ is false for $A$, then stop : $\varphi$ is **not** entailed by $\Gamma$.