Use normal Linux/Unix permissions on your `dude/photos` to make sure that `popolo` can't access them.
Assuming that `popolo` isn't the owner of those files and directories and isn't in the group, then a simple `chmod -R o-rwx dude/photos` should make sure that `popolo` can't access those files.
**Or:**
An alternative way would be to give `popolo` and empty `chroot` home and bind mount all the directories that you _want_ that user to access into that empty `chroot`.
Assuming (again) that `popolo`'s `chroot` home is now `/home/popolo` then:
mkdir /home/popolo/music /home/popolo/movies
mount --bind /srv/ftp/dude/music /home/popolo/music
mount --bind /srv/ftp/dude/movies /home/popolo/movies
As you haven't bind mounted your `dude/photos` directory, `popolo` won't have access to them.