Hint for the first problem: Let $n$ be given, and let $\epsilon\gt 0$. Then there is a $k\gt n$ such that $q_k\lt \epsilon$. What does that say about $\bigcup_{k=n}^\infty A_k$?
**Added:** We first show that for all $n$ there is a $k\gt n$ such that $q_k\lt \epsilon$. This is because there are infinitely many rationals in the interval $0\lt x\lt \epsilon$, and there are only $n$ rationals of the form $q_i$ where $i\le n$.
So for every $\epsilon\gt 0$, there is a $k\gt n$ such that $[\epsilon,1]\subset A_k$. It follows that $\bigcup_{k=n}^\infty A_k$ contains the interval $(0,1]$. For every large enough $n$, $\bigcup_{k=n}^\infty A_k$ does not contain $0$. We conclude that $\bigcap_{n=1}^\infty \bigcup_{k=n}^\infty A_k=(0,1]$.
Hint for the second problem: Use the fact that for every $n$, and for every $\epsilon \gt 0$, there is a $k\gt m$ such that $q_k\gt 1-\epsilon$.