We want to prove that $f'(x)\leq 0$ for all $x\in \mathbb R$.
Fix $x\in \mathbb R$. By Taylor formula we have
$$f(x+h) = f(x)+f'(x)h + h^2\int_0^1(1-t)f''(x+th)dt \geq f(x)+f'(x)h,$$ because $f''(x+th)> 0$.
Suppose $f'(x)>0$. We have
$$f(x+h) \geq f(x)+f'(x)h,$$
and therefore $\lim_{h\to \infty} f(x+h) = \infty$, which is a contradiction.
Therefore, $f(x)\leq 0$.