To remove this question from the unanswered list, here is the answer coming out of the comments.
Let $X_1=X^{sm}$ be the smooth locus, which is open and dense in $Y_0:=X$, which we assume to be reduced. Consider the closed subset $Y_1=Y_0\setminus X_{1}$, take the dense open $X_2=Y_1^{sm}\subset Y_1$, and further $Y_2=Y_1\setminus X_2$, which is closed in $X$ as well. The chain of closed subsets $(Y_i)$ stabilizes by Noetherianity of $X$, and none of the open subsets $X_i\subset Y_{i-1}$ is empty, because the smooth locus of a variety is always dense. So finally $X=\coprod X_i$.