Notice that the problem is symmetric: both players win with equal probability. The chance of a tie is simply $\frac16$, so for (a) the chance that Tim wins is $\frac12 \cdot Pr(\
eg tie) = \frac12 \cdot (1 - \frac16) = \frac5{12}$.
For (b) Rich wins if Tim rolls below a 3, so $\frac13$ is correct. Likewise, (c) is $\frac12$.
For (d) and (e) we use Bayes' theorem: $P(A|B) = \frac{P(A\cap B)}{P(B)}$:
$$Pr(Tim=2 | Rich wins) = \frac{Pr(Tim=2 \cap Rich wins)}{Pr(Rich wins)} = \frac{\frac16\cdot\frac23}{\frac5{12}} = \frac4{15}$$
(e) is basically the same problem.