The Catalan number.
If a's are left parentheses and b's are right parentheses, the condition translates into "there are less then i right parentheses to the left of the i-th left parenthesis".
e.g. For n = 3 we have
$(\ )(\ )(\ ),\ (\ )((\ )),\ ((\ ))(\ ),\ ((\ )(\ )),\ (((\ )))$ or
$a_1b_1a_2b_2a_3b_3,\ a_1b_1a_2a_3b_2b_3,\ a_1a_2b_1b_2a_3b_3, \ a_1a_2b_1a_3b_2b_3,\ a_1a_2a_3b_1b_2b_3$