I would appeal to the compactness theorem. Add to your supposed first order axiomatization the countable set $\exists c\ c \gt 1, \exists c\ c \gt 1+1, \exists c\ c \gt 1+1+1,\ldots$ Any finite subset is satisfied by the Archimedean field because you have finitely many of the new axioms and you just need to take $c$ large enough. Then the whole set must have a model, but that model is non-Archimedean. This model satisfies the original axiomatization, so it does not select only the Archimedean ordered fields.