By definition, $e$ is an edge of $G$ if and only if $e$ is not an edge in $\overline{G}$ (this is a more standard notation for complement). If you have a clique of size $k$ in $G$, then you have $k$ vertices where every possible edge between them is included. Thus, in $\overline{G}$, _none_ of these edges are present, and therefore these $k$ vertices form an independent set of size $k$. Similarly, if you start with an independent set in $\overline{G}$, there is a corresponding clique in $G$.