Here is one possible non-trivial and exceptional prime, the existence or non-existence of which is not yet proven.
It is believed, but not yet proven, that there does not exist positive integers $m$ and $n$ for which $\zeta(1+m/n)$ is a positive integer. However when it comes to prime we can prove a slightly better result i.e.
> _There exists either none or at most only one prime $p$ such that_ _$\zeta(1+p/n)$ is an positive integer for some natural number $n$_.
I believe there is no such prime, but if we are wrong then there will be at most one such prime, making this prime truly exceptional.