If $XX'$ is positive semi-definite, then $L_n$ is convex.
Expand $\left \|Y-X'\beta \right \|_2^2$, we get $F(\beta)=Y'Y-2Y'X'\beta+\beta'XX'\beta$. $F(\beta)$ is convex with respect to $\beta$ when $XX'$ is positive semi-definite. As you know $\| \beta \|_1$ is convex, therefore $L_n$ is the sum of two convex function, it's convex.