The first equality that you don't understand is indeed a MacLaurin series expansion of the characteristic function, using the link between the moments of a random variable and the derivatives of the characteristic function. See < .
So Shalop is right, the $\sigma$ is a little o.
Then you use the fact that $\left(1+\frac{x}{n}\right)^n\rightarrow e^x$. You can take the $\ln$ if it's not clear. Finally, we see $e^{ait}$ as the characteristic function of the distribution $\delta_a$, which is the distribution of a random variable constantly equal to $a$.