Not only would I say that it **is** ethical, I would say that it is an essential part of your research. In general, without that research then you cannot know whether the person is living or deceased. In order to confirm or analyse a DNA match then you will need to research them and their families, and if possible make contact with them.
Making contact with relatives is a big deal. My entry into genealogy involved finding my mother's siblings, all of whom were taken from the family home in 1947, separated, fostered or adopted. This was hugely successful but it meant not just looking at their vital events but all sources related to them, including newspapers, social media, registers of voters, etc.
I have also helped others find living relatives, such as a biological father who left Britain for India, and long-separated families in Wales and Utah.