If $xS_Ry$ and $yS_Rz$, so there are $\\{x_1,..., x_m\\}$ and $\\{ y_1,...,y_n \\}$ such that $xRx_1, x_1Rx_2,..., x_{m-1}Rx_m, x_mRy$ and $yRy_1, y_1Ry_2,..., y_{n-1}Ry_n, y_nRz$. Denote $x_{m+1}:= y$ and $x_{m+i+1}:=y_i$. Therefore, $xRx_1, x_1Rx_2,..., x_{m-1}Rx_m, x_mRx_{m+1}, ..., x_{m+n+1}Rz$. Hence, $xS_Rz$.
Edit:
To solve 2, it's easy to see that asymmetric implies ireflexive. Because if you suppose that $S_R $ is not ireflexive, so there is $aS_Ra$. Therefore, choose $b=a $ and we have $aS_Rb $ and $bS_Ra $. So $S_R $ would not be asymmetric.
Now we are going to prove that if $S_R $ is not asymmetric implies $S_R $ is not ireflexive. If $S_R $ is **not** asymmetric, there are $a_0 $ and $b_0$ such that $a_0S_Rb_0$ and $b_0S_Ra_0$. Therefore, for transitiveness, $a_0 S_R a_0$. Hence $S_R$ is not ireflexive.