If you use the standard normal distribution the random variable must be standardized.
$Z=\frac{X-\mu}{\sigma}$
Therefore
$P(X\leq x)=\Phi\left(\frac{x-\mu}{\sigma} \right)=\Phi\left(\frac{16-\mu}{5} \right)=0.95$
$\Phi\left(z\right)$ is the cdf of the standard normal distribution. $95\%(=100\%-5\%)$ of the other workers earn less than this specific worker.
Taking the inverse of the cdf.
$\frac{16-\mu}{5} =\Phi^{-1}(0.95)$
The table shows that $\Phi^{-1}(0.95)\approx 1.645$.
Now you can solve for $\mu$.