I disagree with Oscar about part 1 of the question. The elements of a list or vector are ordered, but the elements of a set are not. I don’t think many (any?) mathematicians would write $x = \langle x_i \rangle_{i \in S}$ when $S=\\{4,2,8,6\\}$. Since $x_i$ is a common notation for the $i$-th element of a sequence or vector, one might be okay if $S=\\{1,\dots s\\}$, but I would more likely write $x = \langle x_i \rangle_{i=1\dots s}$ (or $\langle x_i \rangle_{i=2,4,6,8}$ ) to make the order clear if there were a reason to use subscript notation.