There are lots of simply connected, closed manifolds which are not Grassmannians of $k$ planes in some $\mathbb{R}^n$.
One way to see this is as follows: the dimension of $G(k,n)$ is $k(n - k)$.
Solving for $k(n -k) = 8$, we get $(k,n) \in \\{ (1,9), (2,6), (4,6), (8,9) \\}$
However, here are five non-homeomorphic $8$-manifolds that are closed and simply connected:
1) $S^2 \times S^2 \times S^2 \times S^2$
2) $S^8$.
3) $S^3 \times S^3 \times S^2$
4) $S^4 \times S^2 \times S^2$
5) $S^6 \times S^2$.
Thus, at least one of these is not homeomorphic to a Grassmannian.
To check that these five products of spheres are not homeomorphic to each other, you can use the Poincare polynomial: <