Everything you have said is correct, but I want to elaborate a little bit on $b)$. There are four cans, two of which are being chosen essentially at random. There are $$\binom{4}{2} = 6$$ possible choices of two cans, and only one of those choices results in two cans of water. Since each pair of cans is equally likely to be chosen, there is a $1/6$ probability that the two cans containing water are chosen.